Calcium ion also has a smaller radius and so a higher charge density giving it a greater polarising power allowing it to distort the bonding 1. Charge Density and Polarising Power of Group 2 Metal Cations. Decomposition becomes more difficult and thermal stability increases. Stability of carbonates increases down group I (alkali) and group II (alkaline earth) metals. Stability of oxides decreases down the group. Group 2 Salts - Solubility & Tests (7:27) Thermal Stability of Group 1/2 Carbonates (8:19) Thermal Stability of Group 1/2 Nitrates (4:38) Thank you The thermal stability of the hydrogencarbonates. Thermal stability of carbonates increases in a group as we move from top to bottom and decreases in a period as we move from left to right. Thermal stability. The carbonate ion has a big ionic radius so it is easily polarized by a small, highly charged cation. Asked by Wiki User. * ⦠So the correct order of stability of carbonates of Group IIA is B a C O 3 > S r C O 3 > C a C O 3 > M g C O 3 . Both carbonates and nitrates of Group 2 elements become more thermally stable down the group. Wiki User Answered . All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. 3. A higher temperature is required to decompose Ba(NO 3) 2 as compared to Mg(NO 3) 2. Solubility. (ii) All the alkaline earth metals form oxides of formula MO. The amount of heat required for the drying procedure of ⦠So C s 2 C O 3 has the highest thermal stability than the other given carbonates. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. BeCO 3 â BeO + CO 2. Thermal decomposition of Group 2 carbonates The ease of thermal decomposition decreases down the group CaCO 3(s) CaO(s) + CO 2(g) Group 2 carbonates decompose on heating to produce group 2 oxides and carbon dioxide gas. 0 0 1. 6. All of these carbonates are white solids, and the oxides that are produced are also white solids. As we go down the group the stability of metal carbonates increases. so, the correct order of thermal stability of given carbonates is: BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Be, Mg and Ca present in second group and K present in the first group. The term "thermal decomposition" describes splitting up a compound by heating it. Nature of carbonates and bicarbonates: Alkali metal carbonates and bicarbonate stability increases down the group. They both have the same number of electrons is their outer shell, but Calcium is further down the group so I would have thought that Calcium is less thermally stable. The respective TG- and DSC-curves are represented. for example,2KNO3 -> 2KNO2 +O2Nitrates of alkaline-earth ⦠The Group 2 hydrogencarbonates like calcium hydrogencarbonate are so unstable to heat that they only exist in solution. All the Group 2 carbonates and their resulting oxides exist as white solids. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. Explanation: New questions in Chemistry. Carbonate Structure. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. Since beryllium oxide is high stable, it makes BeCO 3 unstable. MgCO3 decomposes at 540 C. CaCO3 decomposes at 900 C. SrCO3 decomposes at 1290 C. BaCO3 decomposes at 1360 C. This is because of the increasing size of the cation (ionised metal) as we go down the group. As we move down group 1 and group 2, the thermal stability of nitrate increases. In all cases, for a particular set of e.g. Also, why does thermal stability increase down Group 2? * Due to same reason, carbonates of group-1 are more stable than those of group-2. Solution for group 1 elements with that of group 2 on the basis of the following:⦠Even for hydroxides we have the same observations. It consists of a carbon atom surrounded by three oxygen atom in a trigonal planar arrangement. Thermal decomposition is the term given to splitting up a compound by heating it. MCO 3(s) â MO (s) + CO 2(g) Where M is a Group II element. The thermal stability ⦠Carbonates of group-2 metals are almost insoluble in water and their solubilities further decrease on moving down the group. The thermal stability of Group II carbonates increases as we descend the group. 2012-08-13 15:58:41. I undergo less corrosioncompared to iron. The nitrate ion is less polarised and the compound is more stable. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. Thanks in advance x Thermal decomposition of Group II carbonates. Stability increases down the Group. Thermal stability: * Carbonates are decomposed to carbon dioxide and oxide upon heating. Going down group II, the ionic radii of cations increases. Group 1 or Group 2 compounds, the thermal stability increases down the group as the ionic radius of the cation increases, and its polarising power decreases. Group-2 carbonates are fairly soluble in the solution of CO 2; Thermal Stability. Let's use MgCO 3 as an example. If "X" represents any one of the elements: As you go down the Group, the carbonates have to be heated more strongly before they will decompose The carbonates of alkali metals are stable towards heat. Hence, more is the stability of oxide formed, less will be stability of carbonates. Can you please explain as simply as possible. Correct order of stability of group 2a metal carbonates is 1 See answer mohitrathimr4440 is waiting for your help. Decomposition temperatures and decomposition enthalpies of the four hydroxides increase with increasing atomic weight of the compounds. MgCO 3(s) MgO(s) + CO 2(g) Thermal decomposition is defined as the use of heat to break down a reactant into more than one product Group 2 carbonates ⦠This is because the cation size increases down the Group, this reduces the charge density and polarising power of cation. GROUP 2: THERMAL STABILITY OF THE CARBONATES AND NITRATES 1. a) Both barium carbonate and barium oxide (the product) are white. In fact, these metals can precipitate from their salt solutions as carbonates.Nitrates: Thermal stabilityNitrates of alkali metals,except LiNO3, decompose on strong heating forming nitrites and oxygen. It describes and explains how the thermal stability of the compounds changes as you go down the Group. 2. This decreases the charge density and the ability of the cation to polarize the anion. All the alkaline earth metals form carbonates (MCO 3). All these carbonates decompose on heating to give CO 2 and metal oxide. The increasing thermal stability of Group 2 metal salts is consistently seen. All the carbonates decompose on heating to give carbon dioxide and the oxide. However, carbonate of lithium, when heated, decomposes to form lithium oxide. Beryllium carbonate decomposing most easily. Also, does thermal stability increase or decrease as you go down group 1 (with explanation please)? (You wouldn't see the oxygen also produced). The hydroxides of the Group II metals, which may be used in thermochemical water-splitting cycles, have been investigated thermoanalytically. One may also ask, how does the thermal ⦠Beryllium carbonate is unstable and can be kept only in the atmosphere of CO2. rihu27 rihu27 Answer: down the group the stability of metellic carbonates imcreass. * Thermal stability of group-1 and group-2 carbonates (also of bicarbonates) increases down the group as the polarizing power of the metal ion decreases. Since electropositive character increases from Li to Cs All carbonates and bicarbonate are water soluble and their solubility increases from Li to Cs CHEMICAL PROPERTIES Alkalimetals are highly reactive due to low ionization energy. Add your answer and earn points. The electron cloud of anion is distorted to a lesser extent. See Answer. Small highly charged positive ions distort the electron cloud of the anion. I know stability increases as you go down group 2, please explain why in language a good A level student can understand. I am a metal and placed above iron in the activity series. Why is Magnesium less thermally stable compared to Calcium? The nitrate ion is less polarised and the compound is more stable. Thermal decomposition is the term given to splitting up a compound by heating it. The larger compounds further down require more heat than the lighter compounds in order to decompose. The stability of the metal carbonates can be related to the reactivity series of metals. It describes and explains how the thermal stability of the compounds changes as you go down the Group. Thermal stability of Group II nitrates increases down the This is because the cation size increases down the Group, this reduces the charge density and polarising power of cation. b) lower c) A white solid producing a brown gas and leaving a white solid. This trend is explained in terms of the Group II metal ions ability to polarise the anion, the carbonate ion. Whereas bicarbonates give carbonate, water and carbon dioxide. So what causes this trend? Thermal decomposition is the term given to splitting up a compound by heating it. (ii) Carbonates. Top Answer. 18. Any attempt to get them out of solution causes them to decompose to give the carbonate, carbon dioxide and water. The larger compounds further down require more heat than the lighter compounds in order to decompose. Nitrates of both group 1 and group 2 metals are soluble in water. The solubility of carbonates in water decreases as the atomic number of the metal ion increases. 2) Thermal stability of Group II nitrates increases down the Group. It means the stability increases from M g C O 3 to B a C O 3 . Group 1 compounds tend to be more thermally stable than group 2 compounds because the cation has a smaller charge and a larger ionic radius, and so a lower polarising power. Thermal stability of group 2 carbonates? 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